Hi everyone. Sorry for the delay. Dealing with a new platform takes some getting used to. Given work and play, coming up with some new overclocks has taken some time...
Before I get into it, let me just say: I really appreciate everyone's help here. When you take a noob question, combined with the fact it was posted in the wrong section, you have to be impressed with the membership here in this thread. Maybe my other hobbies, which of course lead me to plenty of other forums far from here, have conditioned me to get used to arrogant, unhelpful clowns so you can color me pleasantly surprised here.
That said, we may be able to mark this thread as "solved." I really think it came down to memory sub-timings. Maybe this thread can help other noobs that are wondering why their skylake isn't scoring as high. Granted I've come to find that my CPU lost--miserably--the silicon lottery (CPU-wise, I'm pretty much settled at 4.6Ghz @ 1.376v and LLC level 2... 4.7Ghz wants close to the Intel-recommended max voltage), I've at least been able to post this:
Intel Core i7-6700K CPU @ 4590.0MHz - 1445 XTU marks on HWBOT
I guess what my original question came down to is, "Is something wrong??" I think that, unequivocally, the answer is a "no." Crappy processor, maybe. I did, however, buy the best RAM I could find. I mean, c'mon, the XMP was rated at 3200 @ 14-14-14-34-2T. Granted that's the conservative mfgr's ratings, I dare you to find anything with a better Mhz/CAS ratio (okay okay, there's probably some RAM out there that's better).
Again, though, comparing apples-to-apples numbers (kind of), I'm still not seeing some of the numbers other folks are. But such is life. I can't bench press my own weight either.
Tl;Dr: No real hardware issues; memory sub-timings very important on Skylake. And, definitely appreciate the helpful folks here on HWBot.